O hydrogen bonds link the molecules, forming infinite chains.
The cations and anions are linked by hydrogen bonds into a
three-dimensional supramolecular network.
The MnII atom is coordinated by four N atoms of two phen ligands, one Cl
atom and one aqua ligand, forming a distorted octahedral geometry. In
the void there is additionally one partly occupied disordered water
molecule.
One uncoordinated water O atom lies on a twofold rotation axis.
The chloride and hydroxide anions are disordered and they interact,
along with the uncoordinated water molecule, with the polycationic chain
to form a three-dimensional, hydrogen-bonded network.
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The piperidine ring adopts a chair conformation in both molecules.
In the void there is additionally one partly occupied disordered water
molecule.
Both H atoms of the amide group participate in intermolecular hydrogen
bonds which link molecules into infinite chains running along the a axis
of the crystal structure. The CoII ion is six-coordinated by four O
atoms of methanol molecules and two water molecules in a distorted
octahedral geometry. O hydrogen bonds, generating a three-dimensional
network. The CoII ion is six-coordinated by four O atoms of methanol
molecules and two water molecules in a distorted octahedral geometry. O
intramolecular interactions.
O hydrogen bonds cross-link these two chains. Cl intermolecular hydrogen
bonding.
In the dianion, one of the sulfate groups is unidentate whereas the
other two chelate the metal atom. N hydrogen bond is also observed. The
CoIII atom and two coordinated water molecules lie on special positions
of site symmetry m. N hydrogen bonding between the imine H atom and the
oxime N atom.
O hydrogen bonds, which link the molecules into chains running parallel
to the c axis.
Both H atoms of the amide group participate in intermolecular hydrogen
bonds which link molecules into infinite chains running along the a axis
of the crystal structure.
O hydrogen bonds stabilize the crystal packing.
The O atoms occupy axial positions and the two halves of the molecule
are related by a twofold axis which passes through the Cd atom.
O hydrogen bonds, generating a three-dimensional network.
The coordination polyhedron of the complex is a slightly distorted
octahedron. In the void there is additionally one partly occupied
disordered water molecule. The O atoms occupy axial positions and the
two halves of the molecule are related by a twofold axis which passes
through the Cd atom.
O hydrogen bonds, generating a three-dimensional network. N hydrogen
bonds into infinite zigzag chains.
The Cl atom and one CH group of the imidazole ring lie on twofold
rotation axes. In the dianion, one of the sulfate groups is unidentate
whereas the other two chelate the metal atom. Acylhydrazines are an
important synthon used to construct hydrogen-bond networks. O hydrogen
bonds link the molecules, forming infinite chains.
The two imino ligands are mutually trans.
N hydrogen bond is also observed. The Cl atom and one CH group of the
imidazole ring lie on twofold rotation axes. The Co atom lies on a
centre of symmetry. Cl intermolecular hydrogen bonding. The coordination
polyhedron of the complex is a slightly distorted octahedron.
The oxazoline ring is disordered over two positions, rendering the
oxygen and nitrogen positions indistinguishable. The ethyl groups of the
solvent ligand are disordered in the void.
The morpholine unit adopts an almost ideal chair conformation. O
hydrogen bonds link the mononuclear units into a three-dimensional
network. O hydrogen bonds, which link the molecules into chains running
parallel to the c axis. In the crystal strucure, cations and anions are
linked into a three-dimensional network architecture by hydrogen bonds.
A twofold rotation axis passes through the coordinated N atom and the
opposite C atom of the pyridyl ring of the ligand, while a threefold
rotation axis passes through the aliphatic N atom. O hydrogen bonds that
link adjacent molecules into one-dimensional chains. O hydrogen bonds,
generating a three-dimensional network.
The CoII ion is six-coordinated by four O atoms of methanol molecules
and two water molecules in a distorted octahedral geometry.
The O atoms occupy axial positions and the two halves of the molecule
are related by a twofold axis which passes through the Cd atom. Cl
interactions, along with S.
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