..."cp -r /dev/ /tmp/RFS/dev/" is wrong! Don't do that.
So, given all the above, I intend to proceed with:
cp -r /dev/ /tmp/RFS/dev/
chroot /tmp/RFS /usr/bin/bash
grub-install /dev/sda
sync
exit
reboot
after I've given people a bit of time to shout at me not to do that if something in what I've written above looks bad.